資源簡介 本資料來自于資源最齊全的21世紀教育網www.21cnjy.com南京學大教育專修學校2013屆高三4月月考數學試題總分:100分 考試時間:90分鐘(理+20分鐘) 學生姓名: _______校區:_________ 授課教師: 學管老師:注意事項:請考生使用藍色或黑色圓珠筆、簽字筆或鋼筆作答。考核內容:考試范圍介紹 高中全部知識點涉及知識及考點 高中全部知識點成績統計:卷Ⅰ 題號 一 二 三 四 總分 總成績分數卷Ⅱ 題號 一 二 三 四 總分分數附加卷 一 二 總分卷Ⅰ(30分鐘,50分)一、填空題(本大題共10小題,每小題5分,共50分.答案寫在答卷紙上.)1.若全集,集合,,則集合= .2.已知復數,,則“”是“為純虛數”的___ __ 條件.(填寫“充要”、“充分不必要”、“必要不充分”、“既不充分也不必要”中的一個)3.如圖所示的算法流程圖中,若則的值等于 .4. 投擲兩顆骰子,得到其向上的點數分別為,,設,則滿足 的概率為 .5.已知正六棱錐的底面邊長為1,側面積為3,則棱錐的體積為 .6.已知角的頂點在坐標原點,始邊與x軸的正半軸重合,角的終邊與單位圓交點的橫坐標是,角的終邊與單位圓交點的縱 坐標是,則= .7.正項等比數列滿足,若存在兩項,使得,則的最小值為8.已知函數的定義域為,且對任意都有,若,則9.已知是橢圓 的右焦點,點在橢圓上,線段與圓相切于點,且,則橢圓的離心率為 .10.記,已知函數為偶函數(為實常數),則函數的零點為 (寫出所有零點)卷Ⅱ(60分鐘,50分)二、解答題:本大題共4小題,共50分.解答應寫出文字說明、證明過程或演算步驟.11.(本題滿分10分)已知,滿足.(1)將表示為的函數,并求的最小正周期;(2)已知分別為的三個內角對應的邊長,若對所有恒成立,且,求的取值范圍.12.(本小題滿分12分)已知橢圓的右頂點為,上頂點為,直線與橢圓交于不同的兩點,若是以為直徑的圓上的點,當變化時,點的縱坐標的最大值為.(1)求橢圓的方程;(2)過點且斜率為的直線與橢圓交于不同的兩點,是否存在,使得向量與共線?若存在,試求出的值;若不存在,請說明理由.13.(本小題滿分14分)已知函數.(1)若,求不等式的解集;(2)若對于一切,不等式恒成立,求的取值范圍.14.(本小題滿分14分)已知函數數列滿足,(1)若,求數列的通項公式;(2)若,為數列的前項和.①求數列的通項公式;②在平面直角坐標系中,記點且,問是否存在,使點三點共線.若存在,求出的關系,若不存在,說明理由.附加卷(20分鐘,20分)15. (本小題滿分5分)選修4-2:矩陣與變換已知矩陣A=,矩陣B=,直線經矩陣A所對應的變換得到直線,直線又經矩陣B所對應的變換得到直線,求直線的方程.16、(本小題滿分5分)選修4-4:坐標系與參數方程橢圓中心在原點,焦點在軸上,離心率為,點是橢圓上的一個動點,若的最大值為,求橢圓的標準方程.17.(本小題滿分10分)由數字1,2,3,4組成五位數,從中任取一個.(1)求取出的數滿足條件:“對任意的正整數,至少存在另一個正整數,且,使得”的概率;(2)記為組成該數的相同數字的個數的最大值,求的概率分布列和數學期望.試卷配套答案一、填空題(本大題共10小題,每小題5分,共50分.答案寫在答卷紙上.)由正弦定理得,,……………8分,,,所以的取值范圍為 …………10分12.解:(1)由,,圓心為以EF為直徑的圓的方程為: ------------------------------------------2即① --------------------------------------------9分M在直線上 ②又,而與共線,可得//③, -------------------------------------------------11分由①②③得, -----------------------------------------13分這與矛盾,故不存在 ---------14分14附加題參考答案15. 選修4-2:矩陣與變換【解】 ……………2分設是上的任意一點,其在BA作用下對應的點為,得變換到的變換公式, ……………3分則即為直線,則得. ……………4分此時,同理可得的方程為,即. ……………5分答:的數學期望為. ……………10分試卷配套屬性表考查點 涉及該考查點的題號 總分 優秀 良好 有較大提高空間集合、復數、概率統計、立幾 1,2,3,4,5 25 20~25 15 0~10函數(導數) 8,10 19 16~19 12~15 0~11三角函數 6,11 15 12~15 9~11 0~10數列 7,13 19 16~19 13~15 0~12解析幾何 9,12 17 14~17 12~13 0~1121世紀教育網 -- 中國最大型、最專業的中小學教育資源門戶網站。 版權所有@21世紀教育網本資料來自于資源最齊全的21世紀教育網www.21cnjy.com南京學大教育專修學校2013年 4月 英語 學科 高三 年級測試卷總分:100分 考試時間:90分鐘 學生姓名: _______校區:_________ 授課教師: 學管老師:__________注意事項:請考生使用藍色或黑色圓珠筆、簽字筆或鋼筆作答。考核內容:考試范圍介紹 高中英語模塊一至模塊十一綜合考查涉及知識及考點 模塊一至模塊十一基礎詞匯、語法、句型等綜合運用;閱讀綜合能力考查成績統計:題號 一 二 三 四 總分 總成績分數題號 五 六 七 八 總分分數第一節:單項填空(共15小題,每小題1分,滿分15分)21. — Have you seen ____ pencil I left it here this morning.—Is it _____black one I think I saw it somewhere.A. a; the B. the; the C. the; a D. a; a22. Jordan kept his illness from his opponents before the final game ________ they might know about it.A. now that B. on condition that C. for fear that D. in order that23. You cannot imagine what great trouble I took ______ your house.A. to find B. finding C. found D. having found24. Mandela, having devoted all his life to the freedom of South African Blacks, is a real fighter for us to_________.A. live up to B. come up to C. make up to D. look up to25. The government has taken some measures to solve the shortage of electricity, but it may be some time _________ the situation improves.A. since B. when C. before D. unless26. What will people die of in 100 years If you think that is a simple question, you ______ attention to the revolution taking place in biotechnology.A. have not been paying B. had not been payingC. were not paying D. will not be paying27. Who ________ a lady like Susan Boyle, once an ordinary woman in Scotland, would achieve overnight success at Britain’s Got Talent Show A. might think B. could thinkC. could have thought D. must have thought28. Don’t you know ______, my dear friend, it is you that she loves A. who B. which C. that D. what ?29. —Hello, John. This is Alice. I'm calling from work. How's your mother feeling —________. Mum is out of hospital, but she has to stay in bed a few more days.A. You're welcome B. That was thoughtful of youC. What a pleasure D. By all means30. There, ____ Mrs. Tailor, stretching out to gather her precious eggs laid by her hen.A. standing on a wooden box was B. was standing on a wooden boxC. on a wooden box was standing D. was on a wooden box standing31. A new study found ______ a teacher has anxiety about math, ______ feeling can influence how his or her female students feel about math.A. when that; which B. that when; thatC. that if; which D. if that; that32. We have dresses of various styles and patterns on sale and you may take ______ suits you best.A. whatever B. whichever C. no matter what D. no matter which33. Watch out for these animals! They could be terrified ______ a sudden loud noise.A. being there B. should there beC. there was D. there have been34. Many grocery stores use misting, a process ________ vegetables are sprayed with water, to keep vegetable fresh.A. which B. that C. what D. where35. You are always telling me I am lazy. Look at your room. What a mess it is!_____.A. The day has eyes, the night has earsB. The great thieves punish the little ones C. That is like the pot calling the kettle blackD. When one will not, two cannot quarrel第二節 完型填空(共20小題;每小題1分,滿分20分)閱讀下面短文,從短文后各題所給的四個選項(A、B、C和D)中,選出最佳選項,并在答題卡上涂黑。The sun shines brightly as I leave school, get into my car, and head for Bradley Hospital. This year, as a senior at Seekonk High School, I have been given the opportunity to leave the usual classroom setting once a week to volunteer.I 36 to spend this valuable time working with mentally disabled children at Bradley Children’s Hospital. I work 37 a teacher in the outpatient/pre-school section, in a classroom with two children— a classroom very different from 38 I have ever known. The difference of this classroom is 39 the children have been diagnosed with a mental disease. One child is autistic and non-verbal(自閉和不說話的), using supportive 40 . The other has a condition called PDD (one step above autism), and is 41 non-verbal. Both children require strong 42 and a lot of attention. This combination creates an atmosphere which is both demanding and sympathetic.My 43 in the classroom is not only to help the teacher, but to become part of the children’s 44 experience. I work one-on-one completing academics with a student. 45 , we work as a group on such activities as cooking, artwork, abstract reasoning. Everyday activities, which may be taken for granted by others, 46 a lot of strength from the children. This has opened my eyes vastly.One of the 47 reasons why I volunteer to take the work is that I desire to help those who are less 48 . However, it has also helped me to realize my competence. I now know that I have the 49 to work with the disabled. I have lost my fear, and I 50 myself a lot more.It is true that my work is very 51 ; there are many days that I 52 Bradley exhausted emotionally and physically. There have been times when I have left on the edge of tears 53 . But pity doesn’t heal, love does. And I have grown to love these children in my own way, 54 I see them only once a week. This experience has been both rewarding and satisfying. I’ve learned also that I do have the ability to make a difference in their lives, no matter how small it may be. One smile makes it all 55 .36. A. promise B. claim C. bother D. choose37. A. for B. on C. alongside D. besides38. A. it B. one C. the other D. which39. A. that B. what C. whether D. how40. A. transportation B. communication C. application D. direction41. A. simply B. completely C. frequently D. naturally42. A. treatment B. commitment C. motivation D. sympathy43. A. choice B. wish C. decision D. role44. A. agricultural B. professional C. technological D. educational45. A. Additionally B. Finally C. Eventually D. Gradually46. A. get back B. build up C. call for D. pick out47. A. chief B. legal C. awkward D. vital48. A. unforgettable B. fortunate C. hopeless D. active49. A. honor B. opportunity C. courage D. ability50. A. believe in B. laugh at C. worry about D. care for51. A. depressing B. challenging C. inspiring D. relaxing52. A. approach B. visit C. leave D. desert53. A. as well B. so far C. in time D. at all54. A. if only B. even though C. now that D. in case55. A. amusing B. enjoyable C. costly D. worthwhile第三部分:閱讀理解(共15小題,每題2分,滿分30分)閱讀下列短文,從每題所給的四個選項(A、B、C和D)中,選出最佳選項,并在答題卡上將該項涂黑。AZoos divide opinion : there are those who think it is cruel to keep animals locked up while others believe zoos are essential for the survival of endangered species.To argue that zoos imprison animals is to misunderstand what zoos are about. Without zoos many of the creatures we love and admire would no longer exist. Every single day,over one hundred animal species vanish. Scientists predict that as early as 2050 one quarter of the Earth’s species will become extinct.Some animals are in danger because they are hunted. Alarmingly, the population of tigers has already fallen by ninety-five percent. Other species are in danger because of a lack of food. For example, there are fewer than 1300 giant pandas left in the wild.Zoos have special breeding programmes to help those animals at risk. These breeding programmes are proving extremely successful. As Irene Shapiro from Zoo and Wildlife Support says, “the Puerto Rican Parrot has grown in numbers from just thirteen to about eighty-five and the Golden Lion Tamarin Monkey, which has almost ceased to exist twenty years ago, has been reintroduced back into the wild. ”Unfortunately, not everyone understands this important role zoos play. For example, Brian Featherstone from the Anti-Zoo Forum says, “I can’t believe we take animals from the wild and put them in cages for the entertainment of the public! We should view them on film or TV in their natural environment.,’However, this misses the point. A zoo does more than display animals to the public. It ensures their survival. Without zoos you would not be able to see many of these animals on TV or anywhere else!56. What’s the writer’s attitude towards zoos A. He shows no opinion either for or against them.B. He thinks that they are unnecessary and cruel.C. He believes they play an important environmental role.D. He expresses a desire that more of them be built.57. The underlined word “vanish” in Paragraph 2 most probably means _____.A. remain B. disappear C. become rarer D. get killed58. According to the passage the world’s tiger population _____.A. will rise by 5% next year B. is relatively stableC. is 95% smaller than in the past D. has fallen to 95%59. According to the passage some people do not agree with zoos because they _____A. are too expensive to run B. put animals in dangerC. do not provide enough food D. keep animals locked up60.According to the writer ,the most important function of the zoo is to _____.A. make a lot of money B. entertain visitorsC. ensure animals’ survival D. educate the publicBToday, bicycles are elegantly simple machines that are common around the world. Many people ride bicycles for recreation, whereas others use them as a means of transportation. The first bicycle was invented in Germany in 1818. Because it was made of wood, it wasn’t very strong nor did it have pedals (腳踏板).Riders moved it by pushing their feet against the ground.In 1839, Kirkpatrick Macmillan, a Scottish blacksmith, invented a much better bicycle. Macmillan’s machine had iron-covered wheels to keep them from getting worn down. He also used foot-operated levers, similar to pedals, so his bicycle could be ridden at a quick pace. It didn’t look much like the modem bicycle, though, because its back wheel was substantially larger than its front wheel. Although Macmillan’s bicycles could be ridden easily, they were never produced in large numbers.In 1861, Frenchman Pierre Michaux and his brother Ernest invented a bicycle with an improved pedal mechanism. They called their bicycle a velocipede,but most people called it a “bone shaker” because of the effect of the wood and iron frame. Despite the impolite nickname, the velocipede was a hit. After a few years, the Michaux family was making hundreds of the machines annually, mostly for fun-seeking young people.Ten years later, James Starley , an English inventor, made several innovations that revolutionized bicycle design. He made the front wheel many times larger than the back wheel, put a gear on the pedals to make the bicycle more efficient,and lightened the wheels by using wire spokes. Although this bicycle was much lighter and less tiring to ride, it was still clumsy, extremely top-heavy,and ridden mostly for entertainment.It wasn’t until 1874 that the first truly modern bicycle appeared on the scene. Invented by another Englishman, H. J. Lawson, the safety bicycle would look familiar to today’s cyclists. The safety bicycle had equal-sized wheels, which made it easier to ride. Lawson also attached a chain to the pedals to drive the back wheel. By 1893,the safety bicycle had been further improved with air-filled rubber tires, a diamond-shaped frame, and easy braking. With the improvements provided by Lawson; bicycles became extremely popular and useful for transportation. Today, they are built, used, and enjoyed all over the world.61.This passage was most likely written in order to _____.A. compare bicycles used for different purposesB. describe the problems early bicycle makers experiencedC. persuade readers to use bicycles for transportationD. tell readers about the early history of the bicycle62.Macmillan covered the wheels of his bicycle with iron to _____A. add weight to the bicycleB. make the bicycle easier to rideC. allow the wheels to last longerD. let the bicycle be more comfortable63. Which of the following bicycle types was invented by James Starley 64 Which of the following statements is true according to the passage A. Two hundred years ago,bicycles did not exist.B. The first bicycle could be ridden at a very quick pace.C. The Michaux brothers called their bicycle a “bone shaker”.D. Macmillan’s machine had wheels with rubber tires.65.The information about bicycles in this passage is arranged according to _____.A. importance B. time C. place D. InterestCSince the end of World War I (WWI) in 1918,Canadians, and millions of others around the world have paused at the 11th hour of the 11th day of the 11th month to honour the sacrifices our soldiers have made in different wars, fighting for the freedoms that we all enjoy today.Known as Remembrance Day, the day originated as a tribute to the soldiers of WWI, a dark period for our young country, which claimed the lives of over 60,000 military personnel and civilians and over 16 million dead worldwide.As there are no more surviving soldiers of WWI,today we rely on the wisdom and words of those soldiers who fought in the wars that followed,and this day now also recognizes their heroic contribution.They tell us to always remember what those brave souls fought for, and all they ask in return is that we never forget.That’s why we wear the red poppy (罌粟花); that’s why when we see a soldier in uniform we should stop him or her and say “Thank you” ; that’s why we take a pause from our busy lives for two short minutes today to honor that request.Yet this message is fading away, year after year.Take for example the terrible decision to allow parents to excuse students from Remembrance Day ceremonies at school.Not only is this disrespectful, it distances the student from his or her classmates.It is difficult to understand why any Canadian parent would want to remove their child from the time-honored tradition of reading the poem In Flanders Fields, while a wreath of poppies is laid.It is more important than ever to teach school-aged children about our history,no matter how violent it was. Sheltering them from the realities of war is a great disservice.Understanding why conflicts happened, or happen today, can help shape choices and decisions they make as adults.Of course, because we live in a free society, we cannot force an individual to do something. It is unfortunate, but some parents now have their child “opt-out” of the services. These people should be reminded they are free to make such choices only because of the men and women the rest of us are remembering.66.Which of the following is true about Remembrance Day A. It’s only held in Canada.B. Its ceremony lasts 11 hours.C. It falls on November 11th each year.D. It’s to celebrate the country’s independence.67. Which of the following is NOT mentioned as a Remembrance Day activity today A. Stopping at 11a.m. to remember the war dead.B. Listening to stories told by WWI soldiers.C. Wearing a red poppy to show respect.D. Showing gratitude to soldiers in uniform.68. What can we learn from the passage A. War history is too violent for school children.B. The writer was once a soldier in the Canadian army.C. Few students are willing to take part in Remembrance Day ceremonies.D. More parents are keeping their children away from frightening war stories.69.The underlined word “It” in the last paragraph probably refers to _____A. the death of so many soldiers in warsB. the fact that there were so many wars after WWIC. people’s ungratefulness for the freedom they haveD. removing children from Remembrance Day events70.The writer believes that .A. the sacrifice of the soldiers should always be rememberedB. Remembrance Day is becoming less important for soldiersC. schools - no longer think Remembrance Day is necessaryD. people should be forced to learn about the realities of war第四部分 任務型閱讀(共10小題;每小題1分,滿分10分)請認真閱讀下列短文,并根據所讀內容在文章后表格中的空格里填入最恰當的單詞。注意:每個空格只填1個單詞。請將答案寫在答題卡上相應題號的橫線上。In Britain all children have to go to school between the ages of 5 and 16. In the US children must go to school from the age of 6 to between the ages of 14 and 16, depending on the state they live in.SubjectIn England and Wales the subjects taught in schools are laid down by the National Curriculum, which was introduced in 1988 and sets out in detail the subjects that children should study and the levels of achievement they should reach by the ages of 7, 11, 14 and 16, when they are tested. The National Curriculum does not apply to Scotland, where each school decides what subjects it will teach.In the US the subjects taught are decided by national and local governments. Whereas British schools usually have prayers and religious instruction, American schools are not allowed to include prayers or to teach particular religious beliefs.ExaminationsAt 16 students in England and Wales take General certificate of Secondary Education (GCSE) examinations. These examinations are taken by students of all levels of ability in all subjects and may involve a final examination, an assessment, or both of these things. At 18 some students take A-level examinations, usually in no more than three subjects. It is necessary to have A levels in order to go to a university .In Scotland students take the Scottish Certificate of Education (SCE) examinations. A year later, they can take examinations called HIGHS, after which they can either go straight to a university or spend a further year at school and take the Certificate of Sixth Year Studies. In Scotland the university system is different from that in England and Wales. Courses usually last four years rather than three and students have to study a larger number of subjects as part of their degree.In the US school examinations are not as important as they are in Britain. Students in High Schools do have exams at the end of their last two years, but these final exams are considered along with the work that the students have done during the school years.Social Events and CeremoniesIn American high schools there is a formal ceremony for graduation . Students wear a special cap and gown and receive a diploma from the head of the school. Students often buy a class ring to ear, and a yearbook, containing pictures of their friends and teachers. There are also special social events at American schools. Sports events are popular, and cheer leaders lead the school in supporting the school team and singing the school song. At the end of their junior year, at age 17 or 18, students held in the evening. The girls wear long evening dresses and the boys wear TUXEDOS.In Britain, there are no formal dances or social occasions associated with school life. Some schools have Speech Day at the end of the school year when prizes are given to the best students and speeches are made by the head teacher and sometimes an invited guest.Title:___71___in Britain and the USIn Britain In the USAges Students ___72____school between theages of 5 and 16. Students go to school from the age of 6 to between the ages of 14 and 16, which __73___ in different states.Subjects * The subjects are required by the National Curriculum in England and Wales* ___74___in Scotland have the right to determine the subjects to be taught * Prayers or particular religiousbeliefs are not ___75___in subjects.* Subjects are decided by national and __76__governmentExams * In England and Wales, one cannot go to university ___77___A levels.* Exams in Scotland are different from __78 in England and Wales *Exams are not so important as they are in Britain.*Students have exams at the end of their last two years.Social events and ceremonies * Schools have no formal dances or social occasions related to school life.* There is Speech Day in some schools, a time for giving prizes and making speeches * A formal ceremony is held for students who ___79___from high school.* Sporting events enjoy _ __80_with students.第五部分 書面表達(滿分25分)目前,不少人在寫作文或交流時喜歡使用網絡語言。就此現象,你班最近舉行了一場討論。請根據下表的提示,客觀地介紹討論的情況及你的觀點。40%的同學認為 60%的同學認為 你的觀點1.有點荒誕,有時讓人無法理解2.違背了漢語的語法規則,對學習毫無幫助 1.幽默,使語言更生動2.有助于表達思想 1… 2. …荒誕ridiculous注意:1. 對所給提示,不要簡單翻譯,可適當增加細節,使行文連貫。2. 詞數150左右。開頭已給出,不計入總詞數。Nowadays, with the development of the Internet, there came a kind of language called Web Language.___________________________________________________________________________________________________________________________________________試卷參考答案單選21-25DCADC 26-30ACCBA 31-35BBBDC完型36-40DCBAB 41-45BCDDA 46-50CABDA 51-55BCABD閱讀理解 56-60 CBCDC 61-65 DCBAB 66-70 CBDDA任務型閱讀71. Education 72. attend 73. varies/ differs 74. schools 75. allowed/ included 76. local 77. without 78. those 79. graduate 80. Popularity書面表達:One possible versionNowadays, with the development of the Internet, there has come a kind of language called Web Language. Recently, our class has held a discussion on whether it’s good for students to use Web Language in writing compositions or communication.40% of the students are not in favor of the idea of using Web Language, thinking it ridiculous to see or hear words which are not commonly used in our daily life. Worse still, it’s hard for them to make themselves understood. In their opinion, it is against Chinese grammar, and it’s not beneficial to students’ studies.However, the rest of the students are fond of it. They think what they say will sound humorous, which makes the language more lively. Moreover, it is of special help for them to express themselves freely.In my opinion, it is a phenomenon worth thinking about. I don’t think it good to use Web Language. It may be fashionable as some think, but you may also make your idea confusing, leaving other people at a loss.21世紀教育網 -- 中國最大型、最專業的中小學教育資源門戶網站。 版權所有@21世紀教育網本資料來自于資源最齊全的21世紀教育網www.21cnjy.com南京學大教育專修學校2013屆高三4月月考語文試題總分:100分 考試時間:60分鐘 學生姓名: _______校區:_________ 授課教師: 學管老師:注意事項:請考生使用藍色或黑色圓珠筆、簽字筆或鋼筆作答。考核內容:考試范圍介紹 高考考綱規定的范圍涉及知識及考點 語言文字運用、古詩文閱讀、名句名篇默寫、現代文閱讀、寫作成績統計:卷Ⅰ 題號 一 二 三 四 五 六 總分 總成績分數一、語言文字運用(30分。選擇題每小題5分)1、下列詞語中加點字的讀音都不相同的一組是 ( )A.編纂 杜撰 百囀千聲 抱頭鼠竄B.箴言 縝密 愛憎分明 蒸蒸日上C.樹陰 蔭庇 應有盡有 鶯歌燕舞D.體憩 修葺 歧路亡羊 詰屈聱牙2、下面各組詞語中沒有錯別字的一組是( )A、溫馨 義氣用事 平心而論 小不忍則亂大謀B、諂媚 坐享其成 因咽廢食 皮之不存,毛將焉附C、龜裂 急流勇退 針砭時弊 差之毫厘,繆以千里D、竣工 戮力同心 一塌湖涂 樹倒猢猻散3、下列各句中加點的成語中使用不恰當的一句是 ( )A. 發展經濟必須合理開發和利用自然資源,為了子孫后代,絕不能做涸澤而漁的事情了。B.因為缺乏位置感,他們根本就不關心老百姓的疾苦,在他們看來,平民意識猶如一塊一文不名的破布。C.新中國的航天事業是白手起家干起來的,經過幾代人的艱苦努力,已取得了令世人矚目的輝煌業績。D.老師,您的好意,我只能敬謝不敏,因為我有自知之明,我做一名普通學生尚可,班長一職實難勝任。4、下列各句中沒有語病的一句是 ( )A.美國“發現”號航天飛機7月1日的發射不僅關系到國際空間站的未來,而且將影響美國航天計劃的正常實施。B.專家表示,南京的城市綠化應該在保持既有特色的同時,走出用單一樹種建設林陰大道的思路。C.由于新加坡是雙語教學,為初去他國的學生做好了語言方面的準備,讓學生在異國他鄉不會有那么強烈的陌生感。D.世界杯期間電視臺往往會播出一些老片應付觀眾,一來避開世界杯的風頭,二來也降低這段“足球月”的播出成本。5.根據下面一段文字,概括出歐洲有關國家爆發主權債務危機的四點內在原因。(每點不超過8個字)(5分)歐洲許多國家國民經濟更多依賴服務業尤其是旅游業。隨著歐洲區域一體化的日漸深入,一些經濟發展水平較低的國家,在社會福利、失業救濟等方面逐漸向發達國家看齊,導致政府巨額的預算赤字。2008年美國爆發的主權債務危機,對這些國家的國民經濟造成巨大沖擊,這些國家逐漸失去繼續借貸的資本。加上歐元區國家實行統一發行貨幣政策,每個成員國無權使用貨幣政策,通過新發債務彌補赤字。于是,主權債務危機就不可避免地爆發了。 6.今年是雷鋒同志犧牲五十周年。1963年,領袖的一聲號召,催生了一場歷久彌高的學習熱潮;而詩人的一首《雷鋒之歌》,唱出了億萬民眾對榜樣的敬仰之情。請寫出《雷鋒之歌》作者的姓名,并為紀念雷鋒同志擬一副不超過30個字的對聯。(5分)⑴作者姓名:______________________⑵對 聯: 二、名句名篇默寫(8分)7.補寫出下列名句名篇中的空缺部分。(每空格1分)⑴___________________,切問而近思,仁在其中矣。(《論語》)⑵___________________,潦倒新停濁酒杯。(杜甫《登高》)⑶釘頭磷磷, ;瓦縫參差,多于周身之帛縷。(杜牧《阿房宮賦》)⑷ ,雜然而前陳者,太守宴也。(歐陽修《醉翁亭記》)⑸桂棹兮蘭槳, 。 ,望美人兮天一方。(蘇軾《赤壁賦》)⑹了卻君王天下事, 。(辛棄疾《破陣子·醉里挑燈看劍》)⑺ ,妙手著文章。(李大釗)三、古詩詞鑒賞(12分)8.閱讀下面一首唐詩,然后回答問題。(12分)塞上聽吹笛高 適霜凈胡天牧馬還,月明羌笛戍樓間。借問梅花何處落 風吹一夜滿關山。 (1)詩人通過寫“聽吹笛”,描寫出了“塞上”一幅怎樣的景象 (6分)答: (2)三、四句在寫法上有什么特色 請結合全詩簡要分析。(6分) 答: 四、閱讀下面的文言文,完成9~12題。(20分,選擇題每個3分) 劉古塘墓志銘〔清〕方苞雍正四年五月望后二日,兄子道希書至,告古塘之喪。昔余成童,從先兄求友閭巷間,得古塘。其后之近邑,歸故鄉,客京師,學同而志相近者,復得數人,而惟古塘為本交。古塘少以雄豪自處,短衣厲飾,惟恐見者知為儒生,而先兄獨義之。余少好氣,數以氣蓋余,心不能平,久之乃見謂直諒。古塘早喪母,家貧,母家給田數十畝。少長,覓食自活,以田歸庶弟。既為諸生,得時譽,學使常以重幣延。歲時歸家,解裝,遇親友,隨手盡,俄而乏絕,饑不得餐,晏如也。年羹堯巡撫四川,固請與偕。議加賦,力爭而止。遂以他故行,曰:“其心神外我矣!能守吾言以期月邪?”及督川陜,復固請以往,再三見,浹月而歸。古塘貌精悍。有與同姓名者,大患鄉里,督學邵嗣堯聞之而未察也,按試呼名,忽注視馮怒,榜笞數十。眾皆嘩,群聚而詬之,嗣堯愧恨,發疾死。古塘始無慍色,既無寬容。嘗語余曰:“士之大閑二:其一義利也,其一利害也。君子懷刑,設子遘禍殃而我退避,以為明哲,可乎?”及余以《南山集》被逮,冒危險以急余,如所言。辛卯鄉試為舉首,以隨部檄,挈余妻子北上,失會試期,后遂絕意進取。年六十有九,終于家。始余出刑部獄,傳客諸公間。諸公計數余兄弟早歲諸同好,數之奇,彼此如一轍。時存者惟彝嘆、古塘,因譜其行及歿而未見余文者,作《四君子傳》。無何彝嘆亦歿,至于今無一存者矣,而余獨留其衰疾之軀,其尚足控揣邪?然吾聞古之為交者,其有失言過行,則相引以為羞;今諸君子各以身名完,未為不幸,獨后死者滋懼耳。古塘子幼,道希與翁君止園紀其喪,余恐不宿,乃豫為志銘。古塘姓劉氏,名捷,懷寧人,流寓江寧。其卒以四月廿五日。某年月日葬于某鄉某原。 (選自《方苞姚鼐集》,有刪改)9.對下列句子中加點詞的解釋,不正確的一項是 ( )A. 饑不得餐,晏如也 晏:安定B. 其心神外我矣 外:疏遠C. 眾皆嘩,群聚而詬之 詬:辱罵D. 數之奇,彼此如一轍 奇:非凡10.下列句子中,全都表現劉古塘為人俠義的一組是 ( )①雄豪自處,短衣厲飾 ②解裝,遇親友,隨手盡③議加賦,力爭而止 ④古塘始無慍色,既無寬容⑤冒危險以急余 ⑥挈余妻子北上,失會試期A.①②④ B. ②⑤⑥ C. ①③⑤ D.③④⑥11.下列對原文有關內容的分析和概括,不正確的一項是 ( )A.年少時的劉古塘,雖為一介書生,但總以英雄豪杰自居,多次在氣概上壓過當年爭強好勝的作者,不過后來兩人卻成為摯友。B.劉古塘在年羹堯擔任四川巡撫期間,受邀入其幕府,但因為與年羹堯在加賦問題上意見相左,他只待了一個月時間便離開了。C.劉古塘早年,因與一個禍患鄉里的人同名同姓,曾遭到行事魯莽的督學邵嗣堯的毒打,督學也為此犯了眾怒,愧恨、發病而死。D.作者出獄后,為當年與自己志趣相投的朋友相繼離世而悲痛萬分,由于擔心自己不久于人世,就預先為亡友劉古塘寫好了墓志銘。12.把文中畫線的句子翻譯成現代漢語。(11分)⑴既為諸生,得時譽,學使常以重幣延。(3分)⑵設子遘禍殃而我退避,以為明哲,可乎?(4分)⑶今諸君子各以身名完,未為不幸,獨后死者滋懼耳。(4分) 五、現代文閱讀閱讀下面的文段,回答13~16題(30分)廬 山玄武諸事椎心,即便身在廬山。當1514年,中年的唐寅自朱宸豪府中佯狂逃出,來到廬山,想必心境便那般復雜。他曾在此留下一幅畫作,迷茫和陰冷的氣息在畫卷上彌漫開來。有誰在畫卷中感觸到了這些?于我,廬山在時間和空間上都已遠離,變得恍惚和不可信。也許我該留下一點印記,一點在廬山的氣息。廬山并不會因一個人的書寫而減石增霧,它只是隨著書寫的展開,從我的心里一點一點消失。那是一次半公差式的游玩。現代人的“旅游”同古人的比起來,總覺得帶了若干輕浮的意味。隨行的人頗多,有肥胖老太,逼仄的山路上她的身軀堵在眼前東挪西挪;有婦人或者少女,不辭辛勞帶著衣服、每到一處景點就興高采烈地更換。這些令人厭倦,而混跡人群之中,卻也自有些污濁的快樂。夜間乘車上山,騰騰的濃霧罩著山路,車燈只能照見前方二三十米的距離,此外一切不見。車窗上很快積了白茫茫的水霧,用手擦開一塊探頭看,黑漆漆一片——那黑的體積和壓力時輕時重逼著眼睛,讓人心驚和下意識地躲——水霧繼而又漫上窗。車進山門停下購票時我跳下來,抽了半支煙。好涼,這是九月。風大,霧無聲無息地、迅疾地撲上來、撲上來。那霧有陰殺之氣,讓人覺得不祥。這是對廬山最初的印象,和內心情感一般茫然。夜里下榻牯嶺鎮一賓館,心中煩悶,出來走動,黑暗步步緊逼,人很快便一點一點退回房間。被褥潮濕,入睡時我想到多年以來我不斷失落的一些事物,它們永不回歸;想到一些具體的人,已經很久不曾記起他們了。此時他們像那些霧一般,無聲無息地、迅疾地撲上來、撲上來。。(選自2005年第9期《散文》,有改動)13.作者寫廬山,為什么要從唐寅在廬山留下的一幅畫作寫起?(6分) 14.怎樣理解文中“現代人的‘旅游’同古人的比起來,總覺得帶了若干輕浮的意味”這句話?(8分) 15.文中兩次提到“撲上來、撲上來”,試比較它們的不同。(8分) 16.針對文最后一自然段“人皆知宋美齡的廬山、彭德懷的廬山,誰曾見有人提過是陶淵明的廬山?那是廬山漸漸喪失的事物”,說一說作者對廬山的認識。(8分) 附加題(15分) 17.閱讀下面文字,按要求作文。 老教授給學生做了個測試。老教授問:“你去山上砍樹,面前有兩棵樹,一棵粗, 一棵細,你砍哪一棵?”大家都說:“當然砍粗的了!”老教授一笑:“那棵粗的是普通的楊樹,而那棵細的卻是紅松,你會砍哪一棵?”同學們一想,紅松比較珍貴,就說: “砍紅松!”老教授又問:“如果楊樹是筆直的,紅松卻七歪八扭,你砍哪一棵?”同學們有些疑惑,就說:“這樣的話,還是砍楊樹!”老教授說:“楊樹雖然筆直,可中間大多空了,你會砍哪一棵?” …… 終于,有人問:“教授,您到底想告訴我們什么呢?”老教授收起笑容,說:“你們怎么就沒人問問自己,到底為什么砍樹?雖然條件不斷變化,可是最終結果取決于你們最初的動機。如果想要取柴,你就砍楊樹,想做工藝品,就砍紅松。” 聽了這番話,大家心中似都有所感悟。 讀完這個故事,你有何感想,請結合自己生活中的感受寫一篇不少于400字的文章。立意自定,文體不限,題目自擬。 試卷配套答案附:參考譯文雍正四年五月十七日,侄子方道希寫的信到了,告訴我劉古塘去世的事。從前我還是孩子的時候,跟著兄長到鄉里訪求朋友,與古塘相識。這以后,到臨近鄉邑(任職),以及初的時候沒有怨怒的神色,之后也沒有表現出寬容。他曾經對我說:“讀書人基本的試卷配套屬性表考查點 涉及該考查點的題號 總分 優秀 良好 有較大提高空間語言文字運用 1—6 30 25-30 18-24 1-17名句名篇默寫 7 8 6-8 5 1-4古詩文閱讀 8、9—12 32 25-32 18-24 1-17現代文閱讀 13—16 30 25-30 20-24 1-19寫作 17 15 12-15 9-12 1-821世紀教育網 -- 中國最大型、最專業的中小學教育資源門戶網站。 版權所有@21世紀教育網本資料來自于資源最齊全的21世紀教育網www.21cnjy.com南京學大教育專修學校2013屆高三4月月考化學試題總分:120分 考試時間:100分鐘校區:_______學生姓名: _______教師姓名:_______學管姓名:_______就讀學校:注意事項:請考生使用藍色或黑色圓珠筆、簽字筆或鋼筆作答。考核內容:考試范圍介紹 必修1 必修2 選修3 選修4 選修5涉及知識及考點 與江蘇高考涉及范圍內容相同成績統計:卷Ⅰ 題號 一 二 總分 總成績分數卷Ⅱ 題號 三 四 總分分數第Ⅰ卷(40分)可能用到的相對原子質量:H-1 C-12 N-14 O-16 Na-23 S-32 Mg-24 Al-27 Cl-35.5 Mn-55 Fe-56 Co-59 Ba-1371、單項選擇題:本題包括10小題,每小題2分,共計20分。每小題只有一個選項符合題意。1.2016年我國將實施新的《環境空氣質量標準》。下列措施有利于改善大氣質量、保護環境的是①出行盡量多開私家車,少乘坐公交車; ②推廣潔凈煤利用技術③優化能源結構,提高能源利用效率; ④生活垃圾露天焚燒A.②③ B.③④ C.①④ D.①②2.分類方法在化學學科的發展中起到了非常重要的作用。下列分類標準合理的是①根據酸分子中含有的氫原子個數將酸分為一元酸、二元酸等②根據反應中是否有電予的轉移將化學反應分為氧化還原反應和非氧化還原反應③根據分散系是否具有丁達爾現象將分散系分為溶液、膠體和濁液④根據反應中的熱效應將化學化學反應分為放熱反應和吸熱反應A.①② B.③④ C.①③ D.②④3、最近俄羅斯科學家用鉿和鎢兩種核素精確測定了地球和月球的年齡,得出月球至少比地球早700萬年形成,它們是根據182 72Hf(鉿—182)和182 74W(鎢—182)兩種核素的含量比例得出的。下列有關鉿—182和鎢—182的關系說法正確的是A、互為同位素 B、都屬于鑭系元素 C、中子數相等 D、原子質量幾乎相同4.將一塊銀白色的金屬鈉放在空氣中會發生一系列的變化:表面迅速變暗→“出汗”→變成白色固體(粉末),下列有關敘述不正確的是A.表面迅速變暗是因為鈉與空氣中的氧氣反應生成了氧化鈉B.“出汗”是因為生成的氫氧化鈉吸收空氣中的水蒸氣在表面形成了溶液C.最后變成碳酸鈉粉末D.該過程的所有化學反應均為氧化還原反應5、某同學如圖所示裝置進行實驗,當滴入液體后出現氣球體積縮小了,則使用的固體和液體試劑可能是( )A、銅與濃硫酸 B、鐵與濃硫酸C、鋁和氫氧化鈉溶液 D、二氧化錳和濃鹽酸6.下列離子方程式表示正確的是A.AgNO3 溶液中加入Cu :Cu+Ag+=Cu2++AgB.NaHCO3溶液中加入CH3COOH:CO32-+2CH3COOH=CO2↑+2CH3COO-+H2OC.0.1mol FeBr2 溶液中通入足量Cl2 :2Fe2++2Br-+2Cl2=2Fe3++Br2+4Cl-D.等體積等物質的量濃度的NaHCO3和Ba(OH)2兩溶液混合:HCO3-+Ba2++OH-=BaCO3↓+H2O7.已知101kPa下有:H2(g)+1/2 O2(g)=H2O(g);△H=-241.8kJ/mol。則下列說法或表達中正確的是( )A、H2的燃燒熱為241.8kJ/molB、H2(g)+1/2O2(g)=H2O(l);△H<-241.8kJ/molC、2H2(g)+O2(g)=2H2O(g);△H>-241.8kJ/molD、1molH2與1/2molO2的總能量小于1molH2O(g)的總能量8.設NA為阿伏伽德羅常數的值。下列敘述正確的是A.25℃,pH=2的HCl溶液中含有H+的數目為0.01NAB.1mol Na2O2固體中含有的陰陽離子總數為4 NAC.1mol碳烯(:CH2)中含有的電子數8NAD.5.6g鐵粉與硝酸反應失去的電子數一定為0.3 NA9.海洋中有豐富的食品、礦產、能源、藥物和水產資源等(如下圖所示)。下列有關說法不正確的是A.從能量轉換角度來看,框圖中的氯堿工業是一個將電能轉化為化學能量的過程B.過程②中結晶出的MgCl2·6H2O要在HCl氛圍中加熱脫水制得無水MgCl2C.在過程③⑤中溴元素均被氧化D.過程①中除去粗鹽中的SO、Ca2+、Mg2+、Fe3+等雜質,加入的藥品順序為:Na2CO3溶液→NaOH溶液→BaCl2溶液→過濾后加鹽酸10.化學中常用圖像直觀的描述化學反應的進程或結果。下列圖像描述正確的是:A.根據圖①可判斷反應CH3OH(g)+H2O(g)=CO2(g)+3H2(g)的ΔH<0B.圖②表示25℃時,用0.1 mol·L-1鹽酸滴定20 mL 0.1 mol·L-1NaOH溶液的pH隨加入酸體積的變化C.根據圖③(S表示溶解度),A點表示T1oC時甲為飽和溶液,乙溶液未飽和。D.根據圖④可判斷可逆反應“A2(g)+3B2(g)2AB3(g)”的ΔH>0二、不定項選擇題:本題包括5小題,每小題4分,共計20分。每小題只有一個或兩個選項符合題意。若正確答案只包括一個選項,多選時,該題得0分;若正確答案包括兩個選項時,只選一個且正確的得2分,選兩個且都正確的得滿分,但只要選錯一個,該小題就得0分。11.萜類物質中有許多都已被用于香料工業。常見的有如下幾種結構(括號內表示④的結構簡式):關于上述四種香料,下列說法正確的是A.②和③均屬于烯烴類 B.①和③互為同系物C.④是②的氧化產物 D.③和④均能發生消去、酯化反應12.電瓶車所用電池一般為鉛蓄電池,這是一種典型的可充電電池,電池總反應式為:則下列說法正確的是A.放電時:負極板上發生了還原反應B.放電時:正極反應是C.充電時:鉛蓄電池的負極應與充電器電源的正極相連D.充電時:陽極反應是13、在恒溫恒容的密閉容器中,發生反應3A(g)+B(g) xC(g)。Ⅰ、將3molA和2molB在一定條件下反應,達平衡時C的體積分數為a;Ⅱ、若起始時A、B、C投入的物質的量分別為n(A)、n(B)、n(C),平衡時C的體積分數也為a。下列說法正確的是A、若Ⅰ達平衡時,A、B、C各增加1mol,則B的轉化率將一定增大B、若向Ⅰ平衡體系中再加入3molA和2molB,C的體積分數若大于a,可斷定x>4C、若x=2,則Ⅱ體系起始物質的量應當滿足3 n(B) =n(A)+3D、若Ⅱ體系起始物質的量當滿足3 n(C) +8n(A)==12 n(B)時,可斷定x=414.下列實驗不能達到預期目的的是代號 實 驗 實驗目的A Cl2、Br2分別與H2反應 比較氯與溴的非金屬性強弱B 同溫下測定相同濃度的Na2CO3,和Na2SO4溶液的酸堿性 比較硫酸與碳酸的酸性強弱C AlCl3、MgCl2溶液中通人過量氨氣 比較鎂與鋁單質的還原性強弱D 同溫下用同一電路分別測定同濃度的鹽酸和某一元酸溶液導電能力 比較該一元酸與鹽酸酸性的強弱15.在25mL 0.1mol·L-1NaOH溶液中逐滴加入0.2mol·L-1CH3COOH溶液,溶液pH變化曲線如圖所示,下列有關離子濃度的比較正確的是A.在A、B間任一點(不含A、B點),溶液中可能有c(Na+)>c(CH3COO-)>c(OH-)>c(H+)B.在B點,a>12.5,且有c(Na+)=c(CH3COO-)=c(OH-)=c(H+)C.在C點,c(CH3COO-)>c(Na+)>c(OH-)>c(H+)D.在D點,c(CH3COO-)+c(CH3COOH)=c(Na+)第Ⅱ卷(非選擇題 共80分)16.(12分)亞氯酸鈉(NaClO2)是一種重要的消毒劑,主要用于水、砂糖、油脂的漂白與殺菌。以下是制取亞氯酸鈉的工藝流程:已知:①NaClO2的溶解度隨著溫度升高而增大,適當條件下可結晶析出。②ClO2氣體只能保持在稀釋狀態下以防止爆炸性分解,且需現合成現用。③ClO2氣體在中性和堿性溶液中不能穩定存在。(1)在無隔膜電解槽中持續電解一段時間后,生成氫氣和NaClO3,請寫出陽極的電極反應方程式: 。(2)反應生成ClO2氣體需要X酸酸化的原因為: 。X酸為 。(3)吸收塔內的溫度不能過高的原因為:(4)吸收塔內ClO2隨著還原劑的不同和溶液酸堿性的變化可被還原為ClO2—或Cl—。ClO2被S2—還原為ClO2—、Cl—的轉化率與溶液pH的關系如右圖所示。請寫出pH≤2時ClO2與S2—反應的離子方程式:。(5)第二步向NaClO3溶液中通SO2的同時通入空氣的原因為: 。(6)從濾液中得到NaClO2●3H2O粗晶體的操作步驟為、 、 。17. (15分)藥物G是一種抗精神病藥物,一種工業合成G的路線如下:(1)有機物B中含氧官能團有 ▲ 、 ▲ 及羥基(填官能團名稱)。(2)寫出反應類型,B→C ▲ ;C→D ▲ 。(3)X的分子式為:C10H13N2Cl,則X的結構簡式為 ▲ 。(4)設計步驟A→B的目的是: ▲ 。(5)寫出同時滿足下列條件的C的一種同分異構體的結構簡式 ▲ 。①苯的衍生物,含有兩個互為對位的取代基;②能發生水解反應,產物之一是甘氨酸,另一種產物能與FeCl3溶液發生顯色反應;③分子中有手性碳原子18.(12分)某銅礦石含氧化銅、氧化亞銅、三氧化二鐵和大量脈石(SiO2),現采用酸浸法從礦石中提取銅,其流程圖如下:已知: ①當礦石中三氧化二鐵含量太低時,可用硫酸和硫酸鐵的混合液浸出銅;②反萃取后的水層是硫酸銅溶液,Cu2+濃度約為50g/L。回答下列問題:(1)礦石用稀硫酸浸出過程中氧化亞銅發生的反應為:Cu2O+2H+===Cu2++Cu+H2O;請寫出該過程中發生的另一個氧化還原反應的離子方程式: 。(2)寫出用惰性電極電解水層的電解總反應方程式: 。(3)循環中反萃取劑B的主要成分是 。(4)某銅礦石樣品中,若僅含氧化亞銅、三氧化二鐵和脈石三種物質。取該礦石樣品200.0g,用100mL1.0mol L—1H2SO4溶液浸取后,還需加入10mL 1.0mol L—1 Fe2(SO4)3溶液才能使銅全部浸出,浸取液經充分電解后可得到 6.4gCu。求銅礦石樣品中氧化亞銅和氧化鐵的質量分數?19.(15分)水合肼作為一種重要的精細化工原料,在農藥、醫藥及有機合成中有廣泛用途。 用尿素法制備水合肼,可分為兩個階段,第一階段為低溫氯化階段,第二階段為高溫水解階段,總反應方程式為:(NH2)2CO +NaClO+2NaOH → H2N—NH2·H2O+NaCl+Na2CO3。主要副反應:N2H4+2NaClO= N2↑+2H2O+2NaCl △H<03NaClO= 2NaCl +NaClO3 △H>0CO(NH2)2 +2NaOH= 2NH3↑+Na2CO3 △H>0【深度氧化】:(NH2)2CO+3NaClO= N2↑+3NaCl+CO2↑+2H2O △H<0實驗步驟:步驟1.向30%的NaOH溶液中通入Cl2,保持溫度在30℃以下,至溶液顯淺黃綠色停止通Cl2。步驟2.靜置后取上層清液,檢測NaClO的濃度。步驟3.傾出上層清液,配制所需濃度的NaClO和NaOH的混合溶液。步驟4.稱取一定質量尿素配成溶液,置于冰水浴。將一定體積步驟3配得的溶液倒入分液漏斗中,慢慢滴加到尿素溶液中,0.5h左右滴完后,繼續攪拌0.5h。步驟5.將步驟4所得溶液,加入5g KMnO4作催化劑,轉移到三口燒瓶(裝置見圖9),邊攪拌邊急速升溫,在108℃回流5 min。步驟6.將回流管換成冷凝管,蒸餾,收集( 108~114℃)餾分,得產品。(1)步驟1溫度需要在30℃以下,其主要目的是 ▲ 。(2)步驟2檢測NaClO濃度的目的是 ▲ 。a.確定步驟3中需NaClO溶液體積及NaOH質量b.確定步驟4中冰水浴的溫度范圍c.確定步驟4中稱量尿素的質量及所取次氯酸鈉溶液體積關系d.確定步驟5所需的回流時間(3)尿素法制備水合肼,第一階段為反應 ▲(選填:“放熱”或“吸熱”)。(4)步驟5必須急速升溫,嚴格控制回流時間,其目的是 ▲ 。(5)已知水合肼在堿性條件下具有還原性(如:N2H4+2I2=N2+4HI)。測定水合肼的質量分數可采用下列步驟:a.準確稱取2.000g試樣,經溶解、轉移、定容等步驟,配制250mL溶液。b.移取l0.00 mL于錐形瓶中,加入20mL水,搖勻.c.用0.l000 mol/L碘溶液滴定至溶液出現微黃色且Imin內不消失,計錄消耗碘的標準液的體積。d.進一步操作與數據處理①滴定時,碘的標準溶液盛放在 ▲ 滴定管中(選填:“酸式”或“堿式”)。②若本次滴定消耗碘的標準溶液為18.00mL,可測算出產品中N2H4-H2O的質量分數為 ▲ 。③為獲得更可靠的滴定結果,步驟d中進一步操作主要是: ▲20.(14分)煤制油是一項新興的、科技含量較高的煤化工技術,發展煤制油對我國而言具有重大意義。下列是煤通過間接液化技術制汽油和丙烯的主要工藝流程圖。已知甲醇制烴的反應原理為:(1)為了提高原料利用率,上述工藝中應控制合成氣中V(CO):V(H2)= 。(2)由二甲醚在催化劑作用下轉化為丙烯的化學方程式為: 。(3)每生產1t甲醇約耗煤1.5t,每生產1 t汽油約需耗2.4t甲醇,2015年我國煤制油將達到1000萬噸,則2015年當年需消耗原煤約 萬噸。(4)采用MTG法生產的汽油中,均四甲苯(1,2,4,5-四甲基苯)質量分數約占4 %~7%,均四甲苯的結構簡式為: 。(5)采用DMTO技術,若獲得乙烯和丙烯及丁烯3種烴,生成丁烯的選擇性(轉化丁烯的甲醇的物質的量與甲醇總物質的量之比)為20%,其余生成乙烯和丙烯,設丙烯的選擇性為x,今有403.2L(標準狀況)合成氣,且完全轉化為甲醇,甲醇轉化為烯烴的總轉化率亦為100%,請作出丙烯的物質的量隨x變化的曲線。21.(12分)本題包括A、B兩小題,分別對應于“物質結構與性質”和“實驗化學”兩個選修模塊的內容。請選定其中一題,并在相應的答題區域內作答。若兩題都做,則按A題評分。A.A、B、C都是元素周期表中的短周期元素,它們的核電荷數依次增大。第2周期元素A原子的核外成對電子數是未成對電子數的2倍,B原子的最外層p軌道的電子為半滿結構,C是地殼中含量最多的元素。D是第四周期元素,其原子核外最外層電子數與氫原子相同,其余各層電子均充滿。請用對應的元素符號或化學式填空:(1)A、B、C的第一電離能由小到大的順序為 。(2)A的最高價氧化物對應的水化物分子中其中心原子采取 雜化。(3)與A、B形成的陰離子(AB—)互為等電子體的分子有 。(4)基態D原子的核外電子排布式為 ,右圖是金屬Ca和D所形成的某種合金的晶胞結構示意圖,則該合金中Ca和D的原子個數比為 。(5)向D的高價態硫酸鹽溶液中逐滴滴加B的氫化物水溶液至過量,先出現藍色沉淀,最后溶解形成深藍色的溶液。寫出此藍色沉淀溶解的離子方程式: 。B由呋哺甲酸脫羧得到呋喃與丙酮在酸性條件下縮合,可得到八甲基四氧雜夸特烯。有關實驗原理及流程如下;步驟1:呋喃的制備八甲基四氧雜夸特烯在圓底燒瓶中放置4.5g呋喃甲酸(100℃升華,呋喃甲酸在133℃熔融,230-232℃沸騰,并在此溫度下脫羧),按圖13安裝好儀器。先大火加熱使呋喃甲酸快速熔化,然后調節加熱強度,并保持微沸,當呋喃甲酸脫羧反應完畢,停止加熱。得無色液體呋喃(沸點:31-32℃,易溶于水)。步驟2:大環化合物八甲基四氧雜夸特烯的合成在25mL錐形瓶中加入2.7mL95%乙醇和1.35mL濃鹽酸,混勻,在冰浴中冷至5℃以下,然后將3.3mL丙酮和1.35mL呋喃的混合液迅速倒入錐形瓶中,充分混勻,冰浴冷卻,靜置得一黃色蠟狀固體。過濾,并用3mL無水乙醇洗滌.用苯重結晶,得白色結晶八甲基四氧雜夸特烯。(1)步驟1中用大火急速加熱,其主要目的是(2)裝置圖中堿石灰的作用是 ▲ ;(3)脫羧裝置中用冰鹽浴的目的是 ▲ ;無水氯化鈣的作用是 ▲ ;(4)合成八甲基四氧雜夸特烯加入鹽酸的目的是 ▲ ;(5)確論產品為八甲基四氧雜夸特烯,可通過測定沸點,還可采用的檢測方法有▲ 。鹽浴 試卷配套答案試卷配套答案第I卷18.(12分)(1)Cu+2Fe3+==2Fe2++ Cu2+(2分)(2)2CuSO4 + 2H2O O2↑+ 2Cu + 2H2SO4(2分)(3)H2SO4(2分)(4)Cu2O:3.6% (3分) Fe2O3:3.2%(3分)19、(15分)(1)防止NaClO(歧化)分解為氯酸鈉和氯化鈉(2分)(2) ac(2分) (3)放熱(2分)(4)減少副反應的發生,提高水合肼的產率(2分)(5)①酸式(2分) ②56.25%(3分)③重復步驟b和c2~3次,依據測得的結果,取平均值。(2分)試卷配套屬性表說明:各考點之間有穿插考查點 涉及該考查點的題號 總分 優秀 良好 有較大提高空間元素及其化合物 4.6.16 16 18--24 13-17 0-12化學反應原理 7.10.12.13.15.18.20 36 33-42 24-33 0-24化學基本概念 1.2.3.21 18 13-16 9-12 0-9有機化合物 12.17 19 10-19 6-9 0-5化學實驗 5.9.14.19. 21 10-19 6-9 0-5CH2OHCH2OHOHCHOCHCH2CHOCH3CHCH2CH2=C(CH3)2① ② ③ ④21世紀教育網 -- 中國最大型、最專業的中小學教育資源門戶網站。 版權所有@21世紀教育網本資料來自于資源最齊全的21世紀教育網www.21cnjy.com南京學大教育專修學校2013屆高三4月月考物理試題總分:120分 考試時間:100分鐘學生姓名: _______ 校區:_________ 就讀學校:注意事項:請考生使用藍色或黑色圓珠筆、簽字筆或鋼筆作答。考核內容:考試范圍介紹 必修一、必修二、選修3-1、選修3-2、選修3-3、選修3-4、選修3-5涉及知識及考點 高考要求考察知識點與考點成績統計:卷Ⅰ 題號 一 二 總分 總成績分數卷Ⅱ 題號 三 四 總分分數卷Ⅰ(31分)一、單項選擇題(每題3分,共15分)1.如圖所示,頂端裝有定滑輪的斜面體放在粗糙水平地面上,A、B兩物體通過細繩連接,并處于靜止狀態(不計繩的質量和繩與滑輪間的摩擦)。現用水平向右的力F作用于物體B上,將物體B緩慢拉高一定的距離,此過程中斜面體與物體A仍然保持靜止。在此過程中,下列說法中正確的是A.水平力F一定變小B.斜面體所受地面的支持力一定變大C.地面對斜面體的摩擦力一定變大D.物體A所受斜面體的摩擦力一定變大2. “空間站”是科學家進行天文探測和科學試驗的特殊而又重要的場所。假設“空間站”正在地球赤道平面內的圓周軌道上運行,其離地球表面的高度為同步衛星離地球表面高度的十分之一,且運行方向與地球自轉方向一致。下列說法正確的有A.“空間站”運行的加速度等于其所在高度處的重力加速度B.“空間站”運行的速度等于同步衛星運行速度的倍C.站在地球赤道上的人觀察到它向西運動D.在“空間站”工作的宇航員因受到平衡力而在艙中懸浮或靜止3.如圖所示,A、B、C、D、E、F為勻強電場中一個邊長為10cm的正六邊形的六個頂點,A、C、D三點電勢分別為1.0V、2.0V、3.0V,正六邊形所在平面與電場線平行。則、A.E點的電勢與C點的電勢相等B.電勢差UEF與電勢差UBC相同C.電場強度的大小為10V/mD.電場強度的大小為20/3V/m4.如圖所示,兩個用相同材料制成的靠摩擦傳動的輪A和B水平放置,兩輪半徑Ra=2Rb,當主動輪A勻速轉動時,在A輪邊緣放置的小木塊恰能相對靜止在A輪邊緣上,若將同一小木塊放在B輪上,欲使木塊相對B輪也靜止,則木塊距B輪轉軸的最大距離為A.Rb/4 B.Rb/3C.Rb/2 D.Rb5.如圖所示,質量為m的滑塊從斜面底端以平行于斜面的初速度v0沖上固定斜面,沿斜面上升的最大高度為H。已知斜面傾角為α,斜面與滑塊間的摩擦因數為μ,且μ二、多項選擇題(每題4分,共16分)6.如圖所示是質譜儀的工作原理示意圖.帶電粒子被加速電場加速后,進入速度選擇器.速度選擇器內相互正交的勻強磁場和勻強電場的強度分別為B和E.平板S上有可讓粒子通過的狹縫P和記錄粒子位置的膠片A1A2.平板S下方有強度為B0的勻強磁場.下列表述正確的是A.質譜儀是分析同位素的重要工具B.速度選擇器中的磁場方向垂直紙面向內C.能通過狹縫P的帶電粒子的速率等于E/BD.粒子打在膠片上的位置越靠近狹縫P,粒子的比荷越小7.質量為0.3kg的物體在水平面上運動,圖中的兩條直線分別表示物體受水平拉力作用和不受水平拉力作用時的速度—時間圖像,則下列說法中正確的是A.物體不受水平拉力時的速度圖像一定是bB.物體受水平拉力時的速度圖像可能是aC.摩擦力一定等于0.2ND.水平拉力一定等于0.1N8.有一種家用電器,圖甲是其電路工作原理圖,當電阻絲接在(V)的交流電源上后,電阻絲開始加熱,當其溫度達到某一數值時,自動控溫裝置P啟動,使電阻絲所接電壓變為圖乙所示波形(仍為正弦波),從而進入保溫狀態。不計電阻絲阻值的變化,則下列說法正確的是A.P啟動后,電阻絲的功率變為原來的一半B.P啟動后,電阻絲所接交變電壓的頻率變為原來的一半C.P啟動后,電壓表的讀數大約是原來的0.5倍D.P啟動后,電壓表的讀數大約是原來的0.7倍9.如圖甲所示,R為電阻箱(0-99.9Ω),置于阻值最大位置,Rx為未知電阻。(1)斷開K2,閉合K1,逐次減小電阻箱的阻值,得到一組R、I的值,并依據R、I值作出了如圖乙所示的圖線;(2)斷開K2,閉合K1,當R調至某一位置時,電流表的示數I1=1.0A;保持電阻箱的位置不變,斷開K1,閉合K2,此時電流表的示數為I2=0.8A。據以上數據可知(安培表內阻不計)A.電源電動勢為3.0 VB.電源內阻為0.5ΩC.Rx的阻值為0.5ΩD.K1斷開、K2接通時,隨著R的減小,電源輸出功率一直增大卷Ⅱ(89分)三、簡答題:本題分必做題(第10、11題)和選做題(第12題)兩部分。共計42分。10.(8分)如圖所示為“用DIS(位移傳感器、數據采集器、計算機)研究加速度和力的關系”的實驗裝置。(1)在該實驗中必須采用控制變量法,應保持___________不變,用鉤碼所受的重力作為小車所受外力,用DIS測小車的加速度。(2)改變所掛鉤碼的數量,多次重復測量。在某次實驗中根據測得的多組數據可畫出a-F關系圖線(如圖所示).①分析此圖線的OA段可得出的實驗結論是_________________________________。②此圖線的AB段明顯偏離直線,造成此誤差的主要原因是( )A.小車與軌道之間存在摩擦 B.導軌保持了水平狀態C.所掛鉤碼的總質量太大 D.所用小車的質量太大11.(10分)某學習小組的同學擬探究小燈泡L的伏安特性曲線,可供選用的器材如下:小燈泡L,規格“4.0V.0.7A”;電流表A1,量程3A,內阻約為0.1Ω;電流表A2,量程0.6A,內阻r2=0.2Ω;電壓表V,量程3V,內阻rV=9kΩ;標準電阻R1,阻值1Ω;標準電阻R2,阻值3 kΩ;滑動變阻器R,阻值范圍O~ 10Ω,;學生電源E,電動勢6V,內阻不計;開關S及導線若干。1 甲同學設計了如圖1所示的電路來進行測量,當通過L的電流為0.46A時,電壓表的示數如圖2所示,此時L的電阻為____Ω。②乙同學又設計了如圖3所示的電路來進行測量,電壓表指針指在最大刻度時,加在L上的電壓值是____V。③學習小組認為要想更準確地描繪出L完整的伏安特性曲線,需要重新設計電路。請你在乙同學的基礎上利用所供器材,在圖4所示的虛線框內補畫出實驗電路圖,并在圖上標明所選器材代號。12.[選做題]本題包括、、C三個小題,請選定其中兩題,并在相應的答題區域內作答。若三題都做,則按A、B兩題評分A.(選修模塊3—3)(12分)(1)(4分)以下說法中正確的是 ( )A.布朗運動是懸浮在液體中的固體分子的無規則運動,間接證實了液體分子的無規則運動B.非晶體和單晶體具有各向異性C.第二類永動機無法制成是因為它違反了熱力學第二定律D.分子間距離為平衡距離時,分子間作用力為零,分子勢能最大(2)(4分)如圖所示,一定質量的理想氣體狀態變化的P-V圖像,平行于P軸。氣體從狀態到的變化過程中內能 (選填“增加”或“減少”),氣體 (選填“吸熱”或“放熱”)。(3)(4分)設在某狀態下二氧化碳氣體的密度為ρ,摩爾質量為M,阿伏加德羅常數為N,將二氧化碳分子看作直徑為D的球,則在該狀態下體積為V的二氧化碳氣體變成固體后體積為多少 B.(選修模塊3—4)(12分)(1)(4分)以下說法正確的是( )A.無論什么波,只要振幅足夠大就可以產生明顯的衍射現象B.打電話時,手機將聲信號轉化成電信號,通過調諧后,把信號發射到基站中轉C.波源與觀察者互相靠近或者互相遠離時,觀察者接收到的波的頻率都會發生變化D.光導纖維外殼折射率大于內芯折射率(2)(4分)圖甲所示是一列沿X軸方向傳播的簡諧橫波在t=0時刻的波形,質點P的振動圖像如圖乙所示,則這列波的傳播速度m/s,這列波向 (選填“+x”或“-x”)方向傳播。(3)(4分)如圖所示,AOB是由某種透明物質制成的圓柱體橫截面(O為圓心)折射率為。今有一束平行光以45°的入射角射向柱體的OA平面,這些光線中有一部分不能從柱體的AB面上射出,設凡射到OB面的光線全部被吸收,也不考慮OA面的反射,求圓柱AB面上能射出光線的部分占AB表面的幾分之幾?C.(選修模塊3—5)(12分)(1)(4分)以下說法中不正確的是 ( )A.衰變發出的α放射線是氦核,具有很強的電離作用和穿透能力。B.一個氫原子從n=3的激發態躍遷到基態時,最多能輻射3種不同頻率的光子C.核力是強相互作用的一種表現,在原子核內核力比庫侖力大得多D.α粒子散射實驗證明了原子核式結構模型(2)(4分)光照射到金屬上時,一個光子只能將其全部能量傳遞給一個電子,一個電子一次只能獲取一個光子的能量,成為光電子,因此極限頻率是由 (選填“金屬”或“照射光”)決定的。如圖所示,當用光照射光電管時,毫安表的指針發生偏轉,若再將滑動變阻器的滑片P向右移動,毫安表的讀數不可能 (選填“變大”、“變小”或“不變”)。(3)(4分)總質量為M的火箭被飛機釋放時的速度為,方向水平。釋放后火箭立即向后以相對于地面的速率u噴出質量為m的燃氣,則噴氣后火箭相對于地面的速度變為多大?此過程中火箭的動能增加了多少?四、計算題:解答時請寫出必要的文字說明、方程式和重要的演算步驟。只寫出最后答案的不能得分,有數值計算的題,答案中必須明確寫出數值和單位(本大題共3小題,共47分)13.(16分)如圖甲所示,質量m=6.0x10 -3kg、邊長L=0.20m、電阻R=1.0Ω的正方形單匝金屬線框abcd,置于傾角α=300的絕緣斜面上,ab邊沿水平方向,線框的上半部分處在垂直斜面向上的勻強磁場中,磁感應強度B隨時間t按圖乙所示的規律周期性變化,若線框在斜面上始終保持靜止,取g=l0m/s2.試求:(1)在0~2.0x10一2s時間內線框中產生的感應電流大小;(2)在t=1.0xl0一2s時線框受到斜面的摩擦力;(3)一個周期內感應電流在線框中產生的平均電功率.14.(15分)如圖所示,在坐標系xOy內有一半徑為a的圓形區域,圓心坐標為O1(a,0),圓內分布有垂直紙面向里的勻強磁場。在直線y=a的上方和直線x=2a的左側區域內,有一沿y軸負方向的勻強電場,場強大小為E.一質量為m、電荷量為+q(q>0)的粒子以速度v從O點垂直于磁場方向射入,當速度方向沿x軸正方向時,粒子恰好從O1點正上方的A點射出磁場,不計粒子重力。⑴求磁感應強度B的大小;⑵粒子在第一象限內運動到最高點時的位置坐標;⑶若粒子以速度v從O點垂直于磁場方向射入第一象限,當速度方向沿x軸正方向的夾角=30°時,求粒子從射入磁場到最終離開磁場的時間t.15.(16分)如圖所示,一塊長為L、質量m的扁平均勻規則木板通過裝有傳送帶的光滑斜面輸送.斜面與傳送帶靠在一起連成一直線,與水平方向夾角θ,傳送帶以較大的恒定速率轉動,傳送方向向上,木板與傳送帶之間動摩擦因數為常數.已知木板處在斜面或者傳送帶上任意位置時,支持力都均勻作用在木板底部.將木板靜止放在傳送帶和光滑斜面之間某一位置,位于傳送帶部位的長度設為x,當x=L/4時,木板恰能保持靜止.(1)將木板靜止放在x=L/2的位置,則木板釋放瞬間加速度多大?(2)木板從x=L/2的位置靜止釋放,始終在滑動摩擦力的作用下,移動到x=L的位置時,木板的速度多大?(3)在(2)的過程中,木塊的機械能增加量設為ΔE,傳送帶消耗的電能設為W,不計電路中產生的電熱,比較ΔE和W的大小關系,用文字說明理由.高中物理三年級四月階段測試卷答案(2)(4分)增加 吸熱(各2分)………………………………………………2分由此得 ………………………………………………1分動能增加量為 ………1分四、計算題14.⑴ 設粒子在磁場中做圓運動的軌跡半徑為R,牛頓第二定律有 (1分)粒子自A點射出,由幾何知識 (1分)解得 (1分)⑵ 粒子從A點向上在電場中做勻減運動,設在電場中減速的距離為y1(2分)得(1分)所以在電場中最高點的坐標為(a,)(1分)⑶ 粒子在磁場中做圓運動的周期 (1分)粒子從磁場中的P點射出,因磁場圓和粒子的軌跡圓的半徑相等,OO1PO2構成菱形,故粒子從P點的出射方向與y軸平行,粒子由O到P所對應的圓心角為 =60°(2分)由幾何知識可知,粒子由P點到x軸的距離S = acos (1分)粒子在電場中做勻變速運動,在電場中運動的時間 (1分)粒子由P點第2次進入磁場,由Q點射出,PO1QO3 構成菱形,由幾何知識可知Q點在x軸上,粒子由P到Q的偏向角為=120°(2分)則粒子先后在磁場中運動的總時間粒子在場區之間做勻速運動的時間 (1分)解得粒子從射入磁場到最終離開磁場的時間15.解:(1)時,(1分)時,摩擦力加倍,(1分)由牛頓運動定律得(2分)(2)利用(2)中圖象,可知摩擦力做功:(3分)由動能定理(3分)得(2分)(注:由于摩擦力與位移成線性關系,所以用“平均摩擦力”ד位移”的計算方式也對.)(3)ΔE小于W(2分)因為傳送帶與木板之間有滑動摩擦,電能有一部分轉為了內能(2分)21世紀教育網 -- 中國最大型、最專業的中小學教育資源門戶網站。 版權所有@21世紀教育網 展開更多...... 收起↑ 資源列表 江蘇省南京學大教育專修學校2013屆高三4月月考化學試題.doc 江蘇省南京學大教育專修學校2013屆高三4月月考數學試題.doc 江蘇省南京學大教育專修學校2013屆高三4月月考物理試題.doc 江蘇省南京學大教育專修學校2013屆高三4月月考英語試題.doc 江蘇省南京學大教育專修學校2013屆高三4月月考語文試題.doc 縮略圖、資源來源于二一教育資源庫